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Can the Lead-acid Battery Compete in Modern Times?

Can the Lead-acid Battery Compete in Modern Times

Can the Lead-acid Battery Compete in Modern Times?

Can the Lead-acid Battery Compete in Modern Times?

The answer is affirmative. Lead-acid is that the oldest reversible battery alive. Unreal by the French doc Gaston Planté in 1859, lead-acid was the primary reversible battery for industrial use. a hundred and fifty years later, we tend to have stilln’t any cost-efficient alternatives for cars, wheelchairs, scooters, golf carts, and UPS systems. The storage battery has maintained a market share in applications wherever newer battery chemistries would be too expensive.
Lead-acid doesn’t lend itself to quick charging. The typical charge time is eight to sixteen hours. A periodic totally saturated charge is important to stop sulfation, and also the battery should always be kept in a very charged state. Going away, the battery in a very discharged condition causes sulfation, and a recharge might not be doable.

Finding the perfect charge voltage limit is important. A high voltage (above a pair of.40V/cell) produces smart battery performance, however, shortens the service life because of grid corrosion on the positive plate. An occasional voltage limit is subject to sulfation on the negative plate. Going away, the battery on float charge for a protracted time doesn’t cause injury.

Lead-acid doesn’t like deep sport. A full discharge causes additional strain, and every cycle robs the battery of some service life. This wear-down characteristic additionally applies to alternative battery chemistries in variable degrees. To stop the battery from being stressed through repetitive deep discharge, a bigger battery is suggested. Lead-acid is cheap; however the operational prices will be above a nickel-based system if repetitive full cycles area unit is needed.

Depending on discharge and operative temperature, the sealed lead-acid provides two hundred to three hundred discharge/charge cycles. The first reason for its comparatively short cycle life is grid corrosion of the positive conductor, depletion of the active material, and growth of the positive plates. These changes area unit is most current at higher operative temperatures. Sport doesn’t forestall or reverse the trend.

The storage battery has one in all rock bottom energy densities, creating it unsuitable for moveable devices. Additionally, the performance at low temperatures is marginal. The self-discharge is concerning four-hundredth per annum, one in all the simplest on reversible batteries. As compared, nickel-cadmium self-discharges this quantity in 3 months. The high lead content makes the lead-acid environmentally unfriendly.

 

Plate thickness

The service life of a storage battery will, in part, be measured by the thickness of the positive plates. The thicker the plates, the longer the life is going to be. Throughout charging and discharging, the lead on the plates gets step by step eaten up away, and also the sediment falls to rock bottom. a load of A battery could be a sensible indication of the lead content and also the expectancy.

The plates of automotive starter batteries square measure regarding zero.040″ (1mm) thick, whereas the standard golf cart battery can have plates that square measure between zero.07-0.11″ (1.8- 2.8mm) thick. Self-propelled vehicle batteries might have plates that exceed zero.250″ (6mm). Most industrial flooded deep-cycle batteries use lead-antimony plates. This improves the plate life, however, will increase gassing and water loss.

 

Sealed lead-acid

 

During the middle Seventies, researchers developed a maintenance-free accumulator which will operate in any position. The liquid solution is gelled into moistened separators and also the enclosure is sealed. Safety valves enable emanation throughout charge, discharge and gas pressure changes.

Driven by totally different market wants, 2 lead-acid systems emerged: the little sealed lead-acid (SLA), conjointly best-known underneath the brand of Gelcell, and also the larger Valve-regulated-lead-acid (VRLA). each batteries ar similar. Engineers could argue that the word ‘sealed lead-acid’ could be a name as a result of no reversible battery is wholly sealed.
Unlike the flooded accumulator, each SLA and VRLA ar designed with an occasional over-voltage potential to ban the battery from reaching its gas-generating potential throughout charge as a result of excess charging would cause gassing and water depletion. Consequently, these batteries will ne’er be charged to their full potential. to cut back dry-out, sealed lead-acid batteries use lead-calcium rather than the lead-antimony.

The optimum in operation temperature for the lead-acid accumulator is 25*C (77*F). Elevated temperature reduces longevity. As a suggestion, each 8°C (15°F) rise in temperature cuts the battery life in 0.5. A VRLA, which might last for ten years at 25°C (77°F), would solely be sensible for five years if operated at 33°C (92°F). a similar battery would abstain once 2½ years if unbroken at a continuing desert temperature of 41°C (106°F).

The sealed lead-acid accumulator is rated at a 5-hour (0.2) and 20-hour (0.05C) discharge. Longer discharge times manufacture higher capability readings owing to lower losses. The lead-acid performs well on high load currents.

Absorbed Glass Mat Batteries (AGM)

 

The AGM could be a newer kind sealed lead-acid that uses absorbed glass mats between the plates. it’s sealed, maintenance-free and therefore the plates ar bolt mounted to face up to in depth shock and vibration. Nearly all AGM batteries ar recombinant, that means they will recombine ninety nine of the element and chemical element. there’s nearly no water is loss.

The charging voltages ar constant as for alternative lead-acid batteries. Even beneath severe overcharge conditions, chemical element emission is below the four-dimensional specified for craft and confined areas. The low self-discharge of 1-3% per month permits long storage before recharging. The AGM prices doubly that of the flooded version of constant capability. due to sturdiness, German high performance cars use AGM batteries in favor of the flooded kind.

Advantages

  • Inexpensive and straightforward to manufacture.
  • Mature, reliable and well-understood technology – once used properly, lead-acid is sturdy and provides dependable service.
  • The self-discharge is among rock bottom of reversible battery systems.
  • Capable of high discharge rates.

Limitations

  • Low energy density – poor weight-to-energy quantitative relation limits use to stationary and wheeled applications.
  • Cannot be keep during a discharged condition
  • the cell voltage ought to ne’er drop below a pair of.10V.
  • Allows solely a restricted range of full discharge cycles
  • compatible for standby applications that need solely occasional deep discharges.
  • lead content and solution create the battery environmentally unfriendly.
  • Transportation restrictions on flooded lead acid
  •  there area unit environmental issues concerning spillage.
  • Thermal runaway will occur if improperly charged.

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